Journal
DALTON TRANSACTIONS
Volume 44, Issue 2, Pages 475-479Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4dt02945c
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Funding
- National Basic Research Program of China [2014CB239402]
- National Natural Science Foundation of China [21476043, 21120102036, 21361130020, 91233201]
- Fundamental Research Funds for the Central Universities [DUT14YQ104]
- Swedish Energy Agency
- K&A Wallenberg Foundation
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Photocatalytic oxidation of organic compounds proceeded efficiently in a hybrid system with ruthenium aqua complexes as catalysts, BiVO4 as a light absorber, [Co(NH3)(5)Cl](2+) as a sacrificial electron acceptor and water as an oxygen source. The photogenerated holes in the semiconductor are used to oxidize molecular catalysts into the high-valent Ru-IV=O intermediates for 2e(-) oxidation.
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