Journal
CURRENT OPINION IN ELECTROCHEMISTRY
Volume 19, Issue -, Pages 106-112Publisher
ELSEVIER
DOI: 10.1016/j.coelec.2019.11.003
Keywords
Electron transfer; Adiabatic; Non adiabatic; Graphene; Semiconductors
Funding
- Deutsche Forschungsgemeinschaft
- RSF [17-1301274]
- RFBR
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Electron transfer reactions are the most important processes at electrochemical interfaces. They are determined by the interplay between the interaction of the reactant with the solvent and the electronic levels of the electrode surface. Theoretical treatments only based on Density Functional Theory calculations are not sufficient. This review emphasizes mainly the effect of the electronic structure of the electrode material on electron transfer under different kinetic regimes. Our goal is to understand experimental results in the framework of a theory valid for arbitrary strengths of electronic coupling.
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