Journal
DALTON TRANSACTIONS
Volume 44, Issue 2, Pages 468-471Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4dt02871f
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Funding
- NSFC [21331003]
- MOE [20120031130001, IRT13022, 13R30]
- 111 project [B12015]
- NSF of Tianjin [13JCZDJC32200]
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Two remarkable pentanuclear 3d-4f clusters of Ln(3)Fe(2) were synthesized and structurally characterized. Magnetic studies indicate that Gd3Fe2 possesses the significant magnetic entropy change (-Delta S-m) of 31.7 J kg(-1) K-1 and slow magnetic relaxation is observed in the anisotropic Dy-analogue.
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