Journal
DALTON TRANSACTIONS
Volume 44, Issue 40, Pages 17686-17695Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5dt02924d
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Funding
- British Heart Foundation [NH/11/8/29253]
- EPSRC [EP/K005499/1]
- Office of Science, Office of Basic Energy Sciences, of the U.S. Department of Energy [DE-AC02-05CH11231]
- Engineering and Physical Sciences Research Council [EP/K039210/1, EP/K005499/1, EP/K031252/1] Funding Source: researchfish
- EPSRC [EP/K031252/1, EP/K039210/1] Funding Source: UKRI
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Solvothermal reaction of Zn(OAc)(2) and 5-methoxy isophthalic acid (H(2)MeOip) in aqueous alcohols ROH (R = H, Me, Et, or Pr-i) affords four different novel coordination polymers. Zn-2(HMeOip)(MeOip)(OAc) (1) forms as a 1D 'ribbon of rings' polymer. Zn-6(MeOip) 4.5(HMeOip)(OH)(2)(H2O)(2)center dot 5.5H(2)O (2) crystallises as a complex 3D framework. Zn(MeOip)(H2O)(2) H2O (3) is a 1D coordination polymer that contains almost planar strips of Zn(MeOip). compound 4, Zn-5(MeOip) 4(OH)(2)(H2O)(4)center dot H2O, obtained from aqueous (PrOH)-Pr-i, crystallises as a 2D polymer containing two crystallographically distinct Zn-5(OH)(2) clusters. Preliminary nitric oxide release experiments have been conducted.
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