Journal
DALTON TRANSACTIONS
Volume 44, Issue 19, Pages 8797-8800Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5dt01311a
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Funding
- National Science Foundation of China [21371036, 91122017, 21001029]
- PCSIRT [IRT1117]
- Shanghai Pujiang Program [14PJD006]
- Shanghai Rising-Star Program [11QA1400300]
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A series of complexes of novel chelating thione-alkene S(eta(2)-C=C)S tridentate ligands bound to late transition metals (Ir, Rh, Pd) were isolated and characterised. Counter-anions play an important role in the binding of the alkene moiety to the metals. Different solvents were observed to affect the stability of the rhodium complexes.
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