Journal
CHEMICAL COMMUNICATIONS
Volume 56, Issue 16, Pages 2403-2406Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc09263c
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Funding
- NSFC of China [21601071, 21471027, 51572116]
- NSF of Jiangsu Province [BK20160211]
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A nanosized Ta/W mixed addendum polyoxometalate (Cs12K3H7[MnTa18Si6W54O231]center dot 61H(2)O) based on the unprecedented {MnTa18} cluster was fabricated successfully under hydrothermal conditions. An excellent electrochemical performance of this compound was found in lithium-ion batteries (LIBs) as an anode material. The discharge capacity was 829.9 mA h g(-1) at a current density of 100 mA g(-1) in the first cycle and stable at 428.4 mA h g(-1) after 100 cycles, which suggests the potential application of this new compound in LIBs.
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