Journal
CHEMICAL COMMUNICATIONS
Volume 56, Issue 16, Pages 2391-2394Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc00593b
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Funding
- MIUR (Italian Ministry of University and Research)
- CRT (Cassa di Risparmio di Torino) foundation
- University of Turin
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The heteroatom-directed lateral lithiation of functionalized toluenes in a choline chloride-based eutectic mixture is reported. The metalations proceed within ultrafast reaction times, with a broad substrate and electrophile scope. The directing groups provide a rapid and high regioselective access to functionalized aromatic derivatives of remarkable synthetic value.
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