4.7 Article

eSynthesis, self-assembly and nonlinear optical activity of selenium-annulated perylene diimide

Journal

CHEMICAL COMMUNICATIONS
Volume 56, Issue 21, Pages 3123-3126

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc10006g

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Funding

  1. National Natural Science Foundation of China [21875157, 21304069, 21790361]

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A novel Se-annulated perylene diimide derivative tethered with polyhedral oligosilsesquioxane (POSS) nanoparticles (POSS-2SePDI-POSS) was designed and prepared. The introduction of selenium atoms endows POSS-2SePDI-POSS with significant fluorescence quenching but enhanced excited-state absorption. As a result, POSS-2SePDI-POSS exhibits a distinct reverse saturable absorption characteristic, suggesting its potential application in optical limiting.

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