4.7 Article

Ring-opening polymerization of cyclohexene oxide using aluminum amine-phenolate complexes

Journal

DALTON TRANSACTIONS
Volume 44, Issue 27, Pages 12098-12102

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5dt00220f

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Funding

  1. NSERC
  2. Memorial University
  3. Canada Foundation for Innovation
  4. RDC-Newfoundland
  5. DAAD Rise

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Remarkably active (down to 0.001% Al) catalysts for ring-opening polymerization of cyclohexene oxide under neat reaction conditions are reported. High molecular weight polymers with uniform dispersity are produced. Kinetic data from NMR studies and MALDI-TOF MS data of the polymers provide some mechanistic insight.

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