Journal
DALTON TRANSACTIONS
Volume 49, Issue 10, Pages 3088-3092Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0dt00235f
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- Stiftelsen for Strategisk Forskning (Sweden)
- Deutsche Forschungsgemeinschaft (Germany) [STO 643/10-1]
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Two new, microporous MOFs of framework composition ((CH3)(2)NH2)(2)[M3O(HHTP)(HHTP center dot)], M = Al3+, Ga3+, H6HHTP = 2,3,6,7,10,11-hexahydroxytriphenylene, are described. Electron diffraction combined with molecular simulations show that these compounds crystallize in the beta-cristobalite structure, containing a new type of trinuclear inorganic building unit for MOFs and radical anions.
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