Journal
RSC ADVANCES
Volume 10, Issue 13, Pages 7927-7932Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0ra00176g
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Funding
- Shanghai Scientific and Technological Innovation Project [18YF1428800]
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We report herein the synthesis of a polymeric photosensitizer and its application in aerobic photooxidative hydroxylation of boronic acids. The polymeric photosensitizer was synthesized by the condensation of anthraquinone-2-carbonyl chloride (AQ-2-COCl) with poly (2-hydroxyethyl methacrylate) (PHEMA). The photo-oxidative hydroxylation of boronic acids using anthraquinone-containing-poly (2-hydroxyethyl methacrylate) (AQ-PHEMA) was then explored and shown to exhibit high efficiency and broad scope. Moreover, AQ-PHEMA could be easily recovered and reused for more than 20 times without significant loss of the catalytic activity.
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