4.7 Article

Influence of lithium concentration on the structure and Li+ transport properties of cubic phase lithium garnets

Journal

DALTON TRANSACTIONS
Volume 44, Issue 2, Pages 539-552

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4dt02861a

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Funding

  1. DRDO, New Delhi, India [ERIP/ER/0804415/M/01/1183/4.11.2009]

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To understand the influence of lithium concentration on the structure and Li+ transport properties of cubic lithium garnets, systematic AC impedance, Raman and powder X- ray diffraction (PXRD) investigations have been carried out on lithium garnets with nominal compositions LixA(3)B(2)O(12) (A = Y3+, La3+, Sr2+, Ba2+; B = Te6+, Ta5+, Zr4+ and 3 <= x <= 7.5). The size of the three dimensional A(3)B(2)O(12) frame is found to be an important factor in determining the capacity of housing and the nature of distribution of lithium atoms among available tetrahedral and octahedral sites in the cubic LixA(3)B(2)O(12) lithium garnets. The Li+ conduction in a cubic phase lithium garnet is primarily dependent upon the concentration of lithium and the nature of distribution of lithium atoms among tetrahedral and octahedral sites. AC impedance analysis of cubic phase LixA(3)B(2)O(12) revealed an increase in the hopping of Li+ with the increase in Li+ concentration, reaches a maximized value for the nominal composition Li7La3Zr2O12 and then decreases with the further increase of lithium concentration.

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