Journal
DALTON TRANSACTIONS
Volume 44, Issue 11, Pages 5170-5178Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4dt03757j
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Funding
- CNRS
- UPMC (university pierre et Marie Curi)
- Labex Michem
- French Ministry of Research
- ANR [Switch-2010-Blan-712]
- ANR E-storic [14-CE05-0002]
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A new family of hetero-tri-metallic complexes [M(CuTb)](n) (M-III = Co, Cr, Fe; n = 1, 2, infinity), composed of three series of three compounds (oligo-and poly-nuclear complexes based on [Cu-Tb] subunits), is presented and fully characterized. These nine compounds, viewed as different assemblies of single-molecule magnet (SMM) building blocks, connected to various hexacyanometalate centers, illustrate how the SMM behavior of the [CuTb] moiety can be modulated via the control of intermolecular interactions. Specifically, the combination of the non-innocent diamagnetic [Co-III(CN)(6)](3-) center with a [Cu-Tb](3+) moiety enabled isolation of the magnetic entities, resulting in an improvement of the SMM behavior (ranging from U-eff = 5-7 cm(-1) to 15-17 cm(-1)).
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