Journal
ORGANIC CHEMISTRY FRONTIERS
Volume 7, Issue 6, Pages 896-904Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9qo01438a
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Funding
- National Natural Science Foundation of China [21602001, 21922109, 21672196, 21831007]
- Start-Up Funding from Nanjing Tech University [39837134]
- Fundamental Research Funds for the Central Universities of China [WK2060190086]
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Cleavage of the C(aryl)-C(alkyl) sigma-bond is important both in academy and industry as it holds the potential to provide straightforward access to a variety of targets from readily available chemical feedstocks such like alkylarenes. However, C(aryl)-C(alkyl) bonds of alkylarenes remain intact under most conventional reaction conditions. In this review, we highlight the results of recent C(aryl)-C(alkyl) bond cleavages that have been induced by homogeneous transition metal reagents, by oxidative cleavages, and by rearrangement.
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