Journal
DALTON TRANSACTIONS
Volume 44, Issue 48, Pages 20839-20842Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5dt04264j
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Funding
- Science Foundation Ireland [12/IP/1703]
- EU-COST action on spin state reactivity [CM1305]
- National University of Ireland
- Cultural Service of the French Embassy in Ireland
- Irish Higher Education Authority
- University College Dublin
- Science Foundation Ireland (SFI) [12/IP/1703] Funding Source: Science Foundation Ireland (SFI)
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Two new paramagnetic ionic liquids (ILs) comprising a mononuclear iron(III) or manganese(III) complex cation, charge balanced by a dicyanamide anion are reported which show a range of spin states. Both are liquids at room temperature and the Fe(III) based IL exhibits a spin crossover close to 300 K. The spin crossover profile is independent of the solvation, and is both air and moisture stable.
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