4.6 Article

A facile route to fabricate double atom catalysts with controllable atomic spacing for the r-WGS reaction

Journal

JOURNAL OF MATERIALS CHEMISTRY A
Volume 8, Issue 5, Pages 2364-2368

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c9ta13192b

Keywords

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Funding

  1. National Natural Science Foundation of China [21908255, 21606260, 21938001, 21961160741, 21425627]
  2. Foundation of China-SINOPEC Joint Fund [U1663220]
  3. Guangdong Provincial Key RD Programme [2019B110206002]
  4. Special fund for Local Science and Technology Development by the Central Government, Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program [2017BT01C102]
  5. Fundamental Research Funds for the Central Universities [16lgpy15, 18lgpy34]
  6. DOE Office of Science [DE-AC0206CH11357]

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Four double atom catalysts (DACs) with controllable interatomic distances were achieved via solventless ball-milling, among which double-atom Ni-2/N-C showed good selectivity and superior catalytic activity to single-atom Ni-1/N-C for r-WGS reactions. The modular character of the synthesis provides a facile route to construct diverse atomic spacings of homo- and hetero-DACs.

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