4.7 Article

Water-soluble Ir(III) complexes of deprotonated N-methylbipyridinium ligands: fluorine-free blue emitters

Journal

DALTON TRANSACTIONS
Volume 44, Issue 35, Pages 15420-15423

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5dt02591e

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Funding

  1. EPSRC [EP/J018635/1, EP/J020192/1]
  2. Royal Society
  3. EPSRC [EP/J020192/1, EP/J018635/1] Funding Source: UKRI
  4. Engineering and Physical Sciences Research Council [EP/J018635/1, EP/J020192/1] Funding Source: researchfish

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New blue or blue-green emitting iridium complexes have been synthesised with cyclometalating ligands derived from the 1-methyl-3-(2'-pyridyl) pyridinium cation. Efficient luminescence is observed in MeCN or aqueous solutions, with a large range of lifetimes in the mu s region and relatively high quantum yields.

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