Journal
CHEMICAL COMMUNICATIONS
Volume 56, Issue 23, Pages 3409-3412Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc00441c
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Funding
- National Natural Science Foundation of China [21701123, 21501133]
- Tianjin Municipal Science and Technology Commission [18JCQNJC06200, 17JCZDJC38000]
- National Key R&D Program of China [2017YFA0700104]
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In this study, the construction of a highly negatively charged layered material [CH3CH2NH3](6)In6S12 (InS-1) by introducing a lacunary cluster as the building block is reported. The pronounced framework negative charge density (5.59 x 10(-3)) and the soft Lewis basic S component endow InS-1 with an effective ion exchange performance toward heavier Sr2+, with a top-level adsorption capacity q(m) of 105.35 mg g(-1). InS-1 exhibits a good exchange activity over pH 3-12, and the Sr2+-laden product can be facilely eluted.
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