Journal
CRYSTENGCOMM
Volume 22, Issue 4, Pages 634-638Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9ce01743g
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Funding
- National Science Centre (SONATA) [DEC-2011/03/D/ST5/05486]
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Host-guest complexation between cucurbit[6]uril and dopamine results in concomitant crystallization of two morphologically distinct supramolecular isomers. Form I appears as prismatic crystals and crystallizes in the P2(1)2(1)2(1) space group. Form II appears as needles and crystallizes in the R (3) over tilde space group. Form I is unstable in solution and spontaneously converts into form II. Additionally, form II undergoes single-crystal to single-crystal dehydration at room temperature mediated by an alteration of the host-guest hydrogen bonding pattern and collective reorganization of dopamine guest molecules.
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