4.7 Article

Synthesis of magnesium ZIF-8 from Mg(BH4)2

Journal

DALTON TRANSACTIONS
Volume 44, Issue 34, Pages 15107-15110

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5dt01183c

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Funding

  1. Ministry of Education, Culture, Sports, Science and Technology, Japan
  2. PRESTO program of the Japan Science and Technology Agency (JST)
  3. Grants-in-Aid for Scientific Research [26708006] Funding Source: KAKEN

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Porous Mg(2-methyl imidazolate)(2) (Mg-ZIF-8) was synthesised from Mg(BH4)(2) as a precursor under an Ar atmosphere. It possesses an uncommon tetrahedral Mg2+-N coordination geometry that is stabilised by the formation of a framework, and it exhibits a Brunauer-Emmett-Teller surface area greater than 1800 m(2) g(-1).

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