Journal
DALTON TRANSACTIONS
Volume 44, Issue 34, Pages 15166-15174Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5dt00079c
Keywords
-
Categories
Ask authors/readers for more resources
Treatment of a series of aromatic NHCs (IMes, SIMes, IPr and SIPr) with trimethylaluminium produced their corresponding Lewis acid-base adducts: IMes center dot AlMe3 (1), SIMes center dot AlMe3 (2), IPr center dot AlMe3 (3), and SIPr center dot AlMe3 (4). These complexes expand the few known examples of saturated NHC stabilised Group 13 complexes. Furthermore, compounds 1-4 show differential stability depending on the nature of the NHC ligand. Analyses of topographic steric maps and NHC %V-Bur were used to explain these differences. All the compounds have been fully characterised by multinuclear NMR spectroscopy, IR and single crystal X-ray analysis together with computational studies.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available