Journal
DALTON TRANSACTIONS
Volume 44, Issue 36, Pages 15976-15983Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5dt01340b
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Funding
- TUM Graduate School
- European Union via ERC [247299]
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Amino-functionalised metal-organic frameworks UiO-66 and -67 were post-synthetically modified with salicylaldehyde. A molybdenum complex was immobilised on the resulting materials. They were characterised by C-13-MAS-NMR, XPS and PXRD to confirm immobilisation and stability. The immobilised complex is an active and reusable catalyst for olefin epoxidation with tert-butyl hydroperoxide (TBHP) as an oxidant. It is shown that the effective pore size, probed with Brunauer-Emmett-Teller (BET) surface area analysis and the number of amino groups affect the diffusion of reactants and products, as well as catalyst recycling.
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