Journal
DALTON TRANSACTIONS
Volume 44, Issue 18, Pages 8649-8659Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5dt00497g
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Funding
- University of Ottawa
- CFI
- NSERC DG
- Vanier Canada Graduate Scholarship
- Autonomous University of Puebla [Y-NAT11-I, Y-NAT12-I, Y-NAT13-I]
- CONACyT Mexico
- Moshinsky Foundation
- Conacyt
- DST, India [DST/INT/AUS/P-47/11]
- UGC
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The synthesis, structural, electronic and magnetic characterization of five dinuclear Co(II) azacryptand compounds (1-5) bridged through different ions are reported. The magnetic exchange interactions, 2J values, obtained from theoretical computations show that the variation of the intermetallic angles and distances lead to antiferromagnetic behaviours. Magneto-structural correlations show a trend, where the angles Co(II)-bridge-Co(II) closer to 180 degrees favour an increase in the superexchange pathway leading to higher AF interaction values.
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