Journal
DALTON TRANSACTIONS
Volume 44, Issue 11, Pages 5153-5159Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5dt00172b
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- University of Duisburg-Essen
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LGa (L = [(2,6-i-Pr-2-C6H3)NC(Me)](2)CH) reacts with elemental tellurium with formation of the Te-bridged compound [LGa-mu-Te](2) 1, whereas the reactions with Ph2Te2 and i-Pr2Te occurred with cleavage of the Te-Te and Te-C bond, respectively, and subsequent formation of LGa(TePh)(2) 2 and LGa(i-Pr)Tei-Pr 3. 1-3 were characterized by heteronuclear NMR (H-1, C-13, Te-125) and IR spectroscopy and their solid state structures were determined by single crystal X-ray analyses.
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