Journal
DALTON TRANSACTIONS
Volume 44, Issue 40, Pages 17767-17773Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5dt03041b
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Funding
- Department of Atomic Energy, (India)
- European Commission ERC Starting Grant (PhotoSi) [278912]
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Three new iridium(III) corrole complexes, having symmetrically and asymmetrically substituted corrole frameworks and judiciously varied axial ligands are prepared and characterized by various spectroscopic techniques including the X-ray structures of two of them. The observed phosphorescence at ambient temperature appears at much longer wavelengths than the previously reported Ir(III) porphyrin/corrole derivatives. Efficiencies of these compounds in the generation of singlet oxygen are also studied for the first time.
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