Journal
DALTON TRANSACTIONS
Volume 44, Issue 25, Pages 11286-11289Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5dt01829c
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Funding
- Royal Society [RG130739]
- Flemish Institute for the Promotion of Innovation by Science and Technology (IWT Vlaanderen) via a Baekeland PhD fellowship [IWT 090272]
- Umicore Group Research
- FWO-Flanders (Research Community Ionic Liquids)
- Seagate Technology (Ireland)
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Temperature-dependent switching of paramagnetism of a cobalt(II) complex is observed in an ionic liquid solution. Paramagnetic and thermochromic switching occur simultaneously due to a reversible change in coordination. This reversible switching is possible in the ionic liquid solution, which enables mobility of thiocyanate anions by remaining mobile at low temperatures and acts as an anion reservoir.
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