Journal
DALTON TRANSACTIONS
Volume 44, Issue 24, Pages 10947-10951Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5dt01338k
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- Japan Society for Promotion of Science (JSPS)
- Ministry of Education, Culture, Science, Sports, and Technology of Japan
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Chiral ligand-modified polyoxometalates (POMs) were successfully synthesized by the introduction of BINOL into the dititanium-substituted POM in an organic medium and characterized by X-ray crystallography, spectroscopy, and elemental analyses. These BINOL-modified POMs were stable in the solution state and showed catalytic activity for asymmetric oxidation of thioanisole.
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