Journal
DALTON TRANSACTIONS
Volume 44, Issue 2, Pages 493-497Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4dt03166k
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Funding
- UGC, India
- Ministerio de Economia y Competitividad (MEC) [CTQ2001-23066]
- Academy of Finland [256259, 265328, 263256]
- Academy of Finland (AKA) [256259, 256259] Funding Source: Academy of Finland (AKA)
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A homochiral helical coordination polymer of copper(II) has been synthesized using achiral precursors via spontaneous symmetry breaking and has been confirmed by single crystal X-ray diffraction and solid-state CD spectroscopy. The variable temperature magnetic measurements indicate the presence of weak ferromagnetic exchange interactions mediated by end-to-end cyanate bridges (J = +0.12 cm(-1)).
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