4.7 Article

A donor-acceptor type macrocycle: toward photolyzable self-assembly

Journal

CHEMICAL COMMUNICATIONS
Volume 56, Issue 28, Pages 3939-3942

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc01350a

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Funding

  1. National Natural Science Foundation of China [21604062]
  2. National Key Research and Development Program of China [2016YFB0401100]

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A water-soluble macrocyclic host is reported, composed of alkoxyanthracene as the donor (D), and 4,4-bipyridiniumas the acceptor (A). The intramolecular D-A structure renders the host highly photostable. However, the introduction of a strong electron-donating guest promotes the photodecomposition of alkoxyanthracene, yielding photolyzable host-guest complexes or aggregates.

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