Journal
CHEMICAL COMMUNICATIONS
Volume 56, Issue 28, Pages 3959-3962Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc09921b
Keywords
-
Categories
Funding
- National Science Foundation [1651686]
- Institute for Basic Science [IBS-R10-A1]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1651686] Funding Source: National Science Foundation
Ask authors/readers for more resources
The manganese hydride dimer, [(2,6-iPr(2)PhBDI)Mn(mu-H)](2), was found to mediate nitrile dihydroboration, rendering it the first manganese catalyst for this transformation. Stoichiometric experiments revealed that benzonitrile insertion affords [(2,6-iPr(2)PBDI)Mn(mu-NCHC6H5)](2) en route to N,N-diborylamine formation. Density functional theory calculations reveal the precise mechanism and demonstrate that catalysis is promoted by monomeric species.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
