Journal
DALTON TRANSACTIONS
Volume 44, Issue 27, Pages 12149-12168Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4dt03916e
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- Deutsche Forschungsgemeinschaft
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An easily accessible formamidinate ligand-bearing titanium complex initially synthesized by Eisen et al. is used as catalyst for intermolecular hydroaminoalkylation reactions of unactivated, sterically demanding 1,1- and 1,2-disubstituted alkenes and styrenes with secondary amines. The corresponding reactions, which have never been achieved with titanium catalysts before, take place with excellent regioselectivity (up to 99 : 1) and in addition, corresponding reactions of 1,3-butadienes with N-methylbenzylamine are also described for the first time.
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