4.7 Article

Degradation of azo dyes under visible light with stable MOF based on tetrastyrene imidazole ligand

Journal

DALTON TRANSACTIONS
Volume 49, Issue 14, Pages 4352-4357

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d0dt00415d

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Funding

  1. Natural Science Foundation of Shandong Province [ZR2018LB019]
  2. National Natural Science Foundation of China [21978158]

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In the present work, a new 3D metal-organic framework (MOF) has been synthesized and characterized. The MOF exhibits good chemical stability in aqueous solutions with the pH scale ranging from 3 to 11. Interestingly, the MOF shows high catalytic activities for the degradation of azo dyes (MO, CR and CBR) under visible light without H2O2. The E-a values of the MOF for MO, CR and CBR degradation are obtained to be 23.49, 52.68 and 15.19 kJ mol(-1), respectively. In addition, the MOF can be reused in the catalytic process without the catalytic activity decreasing obviously.

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