4.7 Article

Reducing the shuttle effect with the interactions of polar TiN and non-polar graphene for lithium-sulfur batteries

Journal

CRYSTENGCOMM
Volume 22, Issue 9, Pages 1555-1559

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c9ce01469a

Keywords

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Funding

  1. National Key R&D Program of China [2016YFB0100100, 2016YFA0200100]
  2. National Science Foundation of China [51972313, 51525206, 51521091]
  3. Strategic Priority Research Program of Chinese Academy of Science [XDA22010602]
  4. Youth Innovation Promotion Association of the Chinese Academy of Sciences [2015150]
  5. China Petrochemical Cooperation [218025]

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Chemical anchoring and facilitated transformation of polysulfides by polar titanium nitride nanoparticles and uniform distribution of sulfur by non-polar graphene showed efficient cooperative interactions for lithium-sulfur batteries, which contributed to the enhanced electrochemical performance of a high initial discharge capacity of 1412 mA h g(-1) (0.2 C) and long-term cyclability.

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