Journal
CHEMICAL COMMUNICATIONS
Volume 56, Issue 25, Pages 3609-3612Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc00664e
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Funding
- UQ ECR Grant [UQECR2057677]
- Australian Research Council Discovery Early Career Award [DE190100803]
- Royal Society [UF150021, RSG\R1\180395]
- University of Canterbury Te Whare Wanangao Waitaha, New Zealand
- Australian Research Council [DP180103874]
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Non-stoichoimetric crystalline ZIF-62 was used as the filler for a 6FDA-DAM polyimide-based composite membrane. In situ melting and vitrification of ZIF-62 was then performed, to yield the ZIF-62 glass phase (a(g)ZIF-62), within the polymer matrix. Focus ion beam scanning electron microscopy (FIB-SEM), thermal characterisation and membrane separation tests demonstrate the filling of voids at the MOF/polymer interface from the liquid phase of ZIF-62.
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