Journal
CHEMICAL COMMUNICATIONS
Volume 56, Issue 25, Pages 3669-3672Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc09998k
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Funding
- Ministerio de Ciencia, Innovacion y Universidades (MICINN) [CTQ2017-85263-R]
- AEI [CTQ2017-85263-R]
- FEDER [CTQ2017-85263-R]
- FEDER (FPU predoctoral grant)
- Instituto de Salud Carlos III (FEDER funds) [ISCIII RETIC REDINREN RD16/0009/0015]
- University of Alcala [CCG2018/EXP-005, CCG2018/EXP-008]
- AEI (FPU predoctoral grant)
- Ministerio de Ciencia, Innovacion y Universidades (MICINN) (FPU predoctoral grant)
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Previously unknown 4a-aza-12a-borachrysene has been synthesized in only four steps. The reactions of this BN-embedded PAH with bromine and organolithium compounds proceed with complete regioselectivity, resulting in the formation of nine derivatives. One of these, a phenylalkynyl-substituted derivative, exhibits a remarkably high fluorescence quantum yield (phi(F) = 0.68).
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