Journal
DALTON TRANSACTIONS
Volume 49, Issue 5, Pages 1351-1364Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9dt04763h
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Funding
- DFG [RO 224/71-1]
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Over the past few decades, beta-diketiminate ligands have been widely used in coordination chemistry and are capable of stabilizing various metal complexes in multiple oxidation states. Recently, the chemistry of aluminum and gallium in their +1 oxidation state has rapidly emerged. NacNacM(i) (M = Al, Ga; NacNac = beta-diketiminate ligand) shows a two coordinate metal center comparable with singlet carbene-like species. The metal center also possesses a formally vacant p-orbital. In this article we present an overview of the last 10 years for aluminum(i) and gallium(i) stabilized by beta-diketiminate ligands that have been widely explored in bond breaking and forming species.
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