4.7 Article

A lead free relaxation and high energy storage efficiency ceramics for energy storage applications

Journal

JOURNAL OF ALLOYS AND COMPOUNDS
Volume 710, Issue -, Pages 436-445

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2017.03.261

Keywords

Energy storage; Dielectric properties; Lead free ceramics; Relaxation

Funding

  1. National Natural Science Foundation of China [51572159]
  2. Chinese Postdoctoral Science Foundation [2016M590916]
  3. Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry
  4. Science and Technology Foundation of Weiyang District of Xi'an City [201605]
  5. Industrialization Foundation of Education Depal Intent of Shaanxi Provincial Government [16JF002]

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In the present work, ternary solid solution ceramics of the (1-x)SrTiO3-x(0.65BaTiO(3)-0.35Bi(0.5)Na(0.5)TiO(3)) (STB100x) were designed and fabricated using a conventional solid-state sintering method. The phase structure, microstructure, dielectric property, relaxation property, ferroelectric property and energy storage property were systematically investigated. The addition of 0.65BaTiO(3)-0.35Bi(0.5)Na(0.5)TiO(3) (BTBNT) could enhance the saturated polarization of the ceramics obviously. All the samples show a slim P-E hysteresis loop, and the sample with x = 0.3 exhibits a high energy storage density of 1.40 J/cm(3) and an energy storage efficiency more than 90%. These results indicate that the STB100x ceramics may be a promising lead free materials for high energy storage density capacitors. (C) 2017 Elsevier B.V. All rights reserved.

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