Electrochemical characteristics of La0.59Nd0.14Mg0.27Ni3.3 alloy with rhombohedral-type and hexagonal-type A2B7 phases

A La0.59Nd0.14Mg0.27Ni3.3 alloy with 72 wt% Gd2Co7-type (3R-A(2)B(7)) and 28 wt% Ce2Ni7-type (2H-A(2)B(7)) phases is prepared by induction melting followed by the annealing at 1148 K. Upon further increasing the annealing temperature to 1248 K, the 3R-A(2)B(7) phase transforms into the 2H-A(2)B(7) phase, forming an alloy with a 97 wt% 2H-A(2)B(7) phase and a 3 wt% 3R-A(2)B(7) phase. Electrochemical measurement shows that the discharge capacity retention of the alloy electrode at the 100(th) cycle increases from 88.5% to 92.4% as the 2H-A(2)B(7) phase increases from 28 wt% to 97 wt%. Compared to the 3R-A(2)B(7) phase, the 2H-A(2)B(7) phase shows a stronger ability to resist amorphousiation during dehydrogenation and has better structural stability. Therefore, the transformation from the 3R-A(2)B(7) phase to the 2H-A(2)B(7) phase stabilizes the structure of the alloy against amorphization and oxidation, thus improving the cyclic stability of the alloy. Electrochemical pressure-composition (P-C) isotherms contain two discharge plateaus; the higher plateau corresponds to the 3R-A(2)B(7) phase and the lower one is associated with the 2H-A(2)B(7) phase. As the 2H-A(2)B(7) phase increases, the high-rate dischargeability of the alloy electrodes increases from 56.8% to 66.3%. (C) 2016 Elsevier B.V. All rights reserved.