Synthesis of cobalt doped ZnO/reduced graphene oxide nanorods as active material for heavy metal ions sensor and antibacterial activity

Cobalt doped ZnO/reduced graphene oxide (Co: ZnO/RGO) nanorods were synthesized by a chemical coprecipitation method. The morphological and physical properties were analyzed by High Resolution Scanning Electron Microscope (HR-SEM), Transmittance Electron Microscope (TEM), Fourier Transform Infra-Red spectroscopy (FTIR), X-Ray Diffraction (XRD) and UV-VIS NIR spectroscopy (UV-VIS NIR). The catalytic activity of synthesized nanostructure toward Cd (II) and Pb (II) ions oxidation was investigated by the electrochemical techniques and Co: ZnO/RGO nanorods exhibited an excellent electrocatalytic oxidation of Cd (II) and Pb (II) ions. Difference Pulse Voltammetry (DPV) studies shown that the fabricated electrode had excellent sensitivity for Cd (II) and Pb (II) ions with the detection limit of 0.94 mg/L (Cd (II)) and 0.83 mg/L (Pb (II)) over a concentration range of 10-90 mg/L. Finally, the antibacterial activity test towards the gram positive (Staphylococcus aureus) and gram negative (Escherichia coli) showed that the Co: ZnO/RGO nanorods have better antibacterial activity compared to ZnO/RGO. (C) 2017 Elsevier B.V. All rights reserved.