Journal
CHEMICAL COMMUNICATIONS
Volume 56, Issue 31, Pages 4300-4303Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc01449d
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- University of East Anglia
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Reaction of Fe(CO)(4)Br-2 with 2-aminopyridine and 2-aminonapthalene yields ferracyclic iron(ii) complexes bearing two CO ligands. Irradiation with visible light releases these two CO molecules. Substitution of a halide in the parent complexes by thioglucose provides significantly enhanced water solublity and raises the quantum yield for CO release by around five times. The complexes show anti-inflammatory activity in a TNF assay in the dark.
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