Journal
JOURNAL OF ALLOYS AND COMPOUNDS
Volume 726, Issue -, Pages 88-94Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2017.07.264
Keywords
Hierarchical architecture; Nitrogen doping; Porous graphene; Carbon nanotube; Hybrid; Lithium ion battery
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Funding
- R&D Convergence Program of NST (National Research Council of Science Technology) [CAP-15-02-KBSI]
- Energy Efficiency & Resources program of the Korea of Energy Technology Evaluation and Planning (KETEP)
- Ministry of Trade, Industry & Energy, Republic of Korea [20152020105770]
- Korea Evaluation Institute of Industrial Technology (KEIT) [20152020105770] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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The carbon nanotubes (CNTs) branched on three-dimensional (3D) macroporous, nitrogen-incorporated reduced graphene oxide (NG)/iron oxide (CNT/NG-Fe) hybrid architectures have been prepared via an ice templating and microwave synthesis. Compared with the pristine RGO, the CNTs can be more readily and uniformly grown on the 3D NG surfaces due to the good electronic conductivity by N-type configurations. As demonstrated by the electrochemical performances, the discharge capacity of the 3D CNT/NG-Fe is 1208 mAh g(-1)at 50 mA g(-1) which is greater than 890 and 820 mAh g(-1) of the CNT/G-Fe and NG. When the rate increases from 100 to 1000 mAh g(-1), the capacity retention reaches 52% of initial capacity corresponding to the discharge capacity of 947 mAh g U After 130 cycles at 100 mA g(-1), the capacity gradually increases to 1020 mAh g(-1) with the Coulombic efficiency of >98.5%. The enhanced capacity, rate capability and cyclic stability of the CNT/NG-Fe are associated with the doping effect of N-configuration and unique hierarchical structure consisting of the dense CNT branches on 3D macroporous continuity. (C) 2017 Elsevier B.V. All rights reserved.
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