Journal
JOURNAL OF ALLOYS AND COMPOUNDS
Volume 722, Issue -, Pages 438-444Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2017.06.126
Keywords
Second harmonic generation; Deep-ultraviolet; CsZn2B3O7 single crystal
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Funding
- CENTEM project [CZ.1.05/2.1.00/03.0088]
- ERDF, Ministry of Education, Youth and Sports OP RDI programme
- Ministry of Education, Youth and Sports under the National Sustainability Programme I through CENTEM PLUS [LO1402]
- MetaCentrum [LM2010005]
- CERIT-SC [CZ.1.05/3.2.00/08.0144]
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The linear and nonlinear optical susceptibility dispersion of CsZn2B3O7 single crystal are comprehensively investigated for a bulk structure in form of single crystal taking into account the influence of the packing structural units. The calculation highlights that the BO3 structural units packing is the main source for the large birefringence in CsZn2B3O7 due to high anisotropic electron distribution, and, hence, it affects the macroscopic second harmonic generation (SHG) coefficients. The large SHG is due to hyperpolarizablity formed by ZnO4 tetrahedra and co-parallel BO3 triangle groups. The absorption edge of CsZn2B3O7 occurs at lambda =218 nm and the optical band gap is estimated to be 5.68 eV that is in good agreement with the experimental data (5.69 eV). Therefore, CsZn2B3O7 is expected to produce a coherent radiation in deep-ultraviolet (DUV) region with SHG of about 1.5 x KDP (1.5x0.39 p. m./V=0.585 p. m./V) that agrees with the measurements. This work is aimed at the report of reliable SHG value and the details of the NLO tensor for bulk CsZn2B3O7 single crystal. (C) 2017 Elsevier B.V. All rights reserved.
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