4.7 Article

Microwave preparation of 3D flower-like MnO2/Ni(OH)2/nickel foam composite for high-performance supercapacitors

Journal

JOURNAL OF ALLOYS AND COMPOUNDS
Volume 700, Issue -, Pages 185-190

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2017.01.037

Keywords

Composite materials; Microwave irradiation; Supercapacitors; Manganese dioxide; Nanostructure

Funding

  1. National Natural Science Foundation of China [21065010, 21365019]
  2. Key Laboratory of Eco-Environment-Related Polymer Materials, Ministry of Education of China, Key Laboratory of Gansu Polymer Materials

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Using a simple microwave irradiation approach, we have produced three-dimensional flower-like manganese dioxide/nickel hydroxide/nickel foam (MnO2/Ni(OH)(2)/NF) composite as supercapacitor electrode. Structural and morphological characterizations are carried out by FT-IR spectrum, X-ray diffraction (XRD) and scanning electron microscopy (SEM). The electrochemical properties of MnO2/ Ni(OH)(2)/NF electrode are studied with cyclic voltammetry(CV), galvanostatic charge-discharge analysis and electrochemical impedance spectroscopy(EIS). The results reveal that the MnO2/Ni(OH)(2)/NF electrode exhibits a high specific capacitance of 506 F/g at 16.7 A/g and excellent capacitance retention of 96% after 7000 cycles at an ultrahigh current density of 60 A/g, which suggest the composite has promising applications as an efficient electrode for electrochemical capacitors. (C) 2017 Elsevier B.V. All rights reserved.

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