Journal
JOURNAL OF ALLOYS AND COMPOUNDS
Volume 693, Issue -, Pages 373-380Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2016.09.156
Keywords
Nano-superstructures; Mechanical stirring; Graphene coating; Electrochemical properties
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Funding
- National Natural Science Foundation of China [21471114, 21101118]
- Science & Technology Commission of Shanghai Municipality [14DZ2261100]
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The Fe3O4/MnO2/RGOs (Reduced graphene oxide) sandwich-like nano-superstructures reported in this article were fabricated by using an eco-friendly mechanical stirring route at room temperature without any catalysts or templates. In this nano-superstructure, three-dimensional (3D) hierarchical MnO2 shell was assembled by two-dimensional (2D) nanoplates and Fe3O4/MnO2 core-shell was coated by RGO layers. The sandwich-like nano-superstructures show better electrochemical performance comparing to the pure MnO2 and Fe3O4/MnO2 nanoparticles. The maximum specific capacitance can reach 77.5 F/g at the current density of 0.5 A/g and maintain 35.0 F/g (55% of SC at 0.5 A/g) at the current density of 20 A/g. It was found that the electrocapacitive performances of the Fe3O4/MnO2/RGO electrodes are highly affected by the connection effectiveness between Fe3O4/MnO2 particles and graphene layers. (C) 2016 Elsevier B.V. All rights reserved.
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