Journal
CHEMICAL COMMUNICATIONS
Volume 56, Issue 34, Pages 4732-4735Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc01293a
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A mixture of pathways including the use of catalyst was proposed for a dirhodium-mediated triazole activation-cycloaddition. This proposal was supported by the results of density functional theory (DFT) calculations, and was indicated to involve a non-catalyzed cleavage of the triazole N-N bond followed by a dirhodium-assisted denitrogenation. Electron-deficient carboxylates were found to be favourable for the rate-determining denitrogenation step.
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