Journal
CRYSTENGCOMM
Volume 22, Issue 17, Pages 2895-2899Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0ce00379d
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Funding
- Russian Science Foundation [19-73-00336]
- Russian Science Foundation [19-73-00336] Funding Source: Russian Science Foundation
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Herein, uncommon SCSC transitions within a mononuclear complex when desolvation provokes subtle changes in the molecular structure without alteration in nuclearity are reported. Namely, the stepwise kappa(1) -> kappa(2) recoordination of a carboxylate ligand with an increase in CN from 7 to 8 was shown to occur through an unstable phase with a 7 + 1 coordination detected via an original technique.
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