Extended thermodynamics and microstructures of four-dimensional charged Gauss-Bonnet black hole in AdS space

The discovery of new four-dimensional black hole solutions presents a new approach to understand the Gauss-Bonnet gravity in low dimensions. In this paper, we test the Gauss-Bonnet gravity by studying the phase transition and microstructures for the four-dimensional charged anti-de Sitter black hole. In the extended phase space, where the cosmological constant and the Gauss-Bonnet coupling parameter are treated as thermodynamic variables, we find that the thermodynamic first law and the corresponding Smarr formula are satisfied. Both in the canonical ensemble and grand canonical ensemble, we observe the small-large black hole phase transition, which is similar to the case of the van der Walls fluid. This phase transition can also appear in the neutral black hole system. Furthermore, we construct the Ruppeiner geometry, and find that besides the attractive interaction, the repulsive interaction can also dominate among the microstructures for the small black hole with high temperature in a charged or neutral black hole system. This is quite different from the five-dimensional neutral black hole, for which only dominant attractive interaction can be found. The critical behaviors of the normalized scalar curvature are also examined. These results will shed new light into the characteristic property of four-dimensional Gauss-Bonnet gravity.