Journal
DALTON TRANSACTIONS
Volume 49, Issue 17, Pages 5420-5423Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0dt00842g
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Funding
- Georgia Institute of Technology
- Department of Energy, Heavy Element Chemistry Program [DE-SC0019385]
- CONACYT Graduate Fellowship
- U.S. Department of Energy (DOE) [DE-SC0019385] Funding Source: U.S. Department of Energy (DOE)
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We report the synthesis of tetrameric Cu(I) and Ag(I) homoleptic complexes supported by the tris(piperidinyl)imidophosphorane [NP(pip)(3)](1-) and [NP(1,2-bis-Bu-t-diamidoethane)(NEt2)](1-) ligands. These complexes demonstrate the redox stability of the imidophosphorane ligands to oxidizing salts, and the silver complexes can, in turn, serve as oxidative transmetallation reagents for the isolation of tetravalent cerium complexes from cerium metal or trivalent cerium precursors.
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