Journal
DOKLADY CHEMISTRY
Volume 490, Issue 1, Pages 1-5Publisher
MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S0012500820010012
Keywords
calixarenes; azides; imidazolium salts; chloromethalation
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Funding
- Russian Science Foundation [19-13-00095]
- Russian Science Foundation [19-13-00095] Funding Source: Russian Science Foundation
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A procedure for the chloromethylation of lipophilic distally di-O-substituted calix[4]arene derivatives has been developed to prepare dichloromethyl derivatives of calix[4]arenes with long-chain alkyl fragments in cone configuration in high yields. From the chloromethylated derivatives, ammonium/imidazolium salts containing azidopropyl moieties have been synthesized in high yields. The structure of all obtained compounds has been established by 1D and 2D NMR, IR spectroscopy, and MALDI spectrometry. They can be further used as precursors of polytriazole/polyimidazole polymer species as promising carriers for metal-complex catalysis.
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