3.8 Article

Thermal stability of a vegetable oil-based thermal fluid at high temperature

Publisher

ROUTLEDGE JOURNALS, TAYLOR & FRANCIS LTD
DOI: 10.1080/20421338.2020.1732080

Keywords

refined Jatropha curcas oil; heat transfer fluids; thermal stability; vegetable oils

Funding

  1. Deutscher Akademischer Austauschdienst [57313342/2016]

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Synthetic and mineral oils are widely used in high temperature processes (above 200 degrees C) as heat transfer fluids or thermal storage materials. Mineral oils are essentially derived from petroleum that is depleting and synthetic oils are expensive. Furthermore, these oils are toxic to the environment. Today, with environmental concerns, vegetable oils have gained considerable interest. Vegetable oils are renewable, environmentally friendly and non-hazardous resources. Refined Jatropha curcas oil, a vegetable oil, has been identified as a possible thermal oil for high temperature applications such as concentrating solar power. The vegetable oil was thermally aged at 210 degrees C for up to 2160 h. The volatile materials were below 5% from 100 degrees C to 300 degrees C. The specific heat capacity remained constant at 2.4 kJ center dot kg(-1)center dot degrees C-1 and had a density increase of 2%. The viscosity of aged oil at 100 degrees C was quite similar to that of the new oil. The flash point was around 175 degrees C after 2160 h versus 220 degrees C for the new oil. Based on these results, refined Jatropha curcas oil presents real potential as a heat transfer fluid and thermal storage material.

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